京都大学化学研究所研究者情報   [ English | Japanese ]


登阪 雅聡 (とさか まさとし)

材料機能化学研究系 高分子制御合成
准教授
博士(工学)
URL:
E-mail: tosaka@scl.kyoto-u.ac.jp
Tel: 0774-38-3062
Fax: 0774-38-3067

研究・教育歴
    1989.3 京都大学大学院工学研究科修士課程修了
    2000.1 京都大学博士(工学)
    1989.4〜1995.3 旭化成工業(株)社員
    1995.4〜2007.3 京都大学化学研究所助手
    2007.4〜2012.9 京都大学化学研究所助教(名称変更)
    2012.10~ 京都大学化学研究所准教授
    2001.4〜2002.3 ドイツオルデンブルグ大学特別研究員
    2002.4〜2005.3 兵庫県立工業技術センター客員研究員を兼務
    2005.9〜2006.3 立命館大学 非常勤講師を兼務
専門分野
    高分子物理
主な研究テーマ
  1. 高分子結晶構造解析
  2. 線状高分子の結晶化
  3. 高分子ネットワークの伸長結晶化
  4. 高分子配向膜上への散逸構造形成
主な論文・著書
  1. 登阪雅聡, 丸山隆之, 放射光を用いた、天然ゴム亀裂先端における伸張誘起結晶のWAXDマッピング解析 日本ゴム協会誌 90, 359-362 (2017)
  2. 登阪雅聡, シリコーンゴムにおけるメゾ相の形成と結晶化 日本ゴム協会誌 90, 329-332 (2017)
  3. 登阪雅聡, 架橋天然ゴムの伸長結晶化キネティクス Kinetics of Strain-induced Crystallization in Cross-linked Natural Rubber 日本接着学会誌 J. Adhesion Soc. Jpn. 51(10), 450-455 (2015)
  4. Gros, Alice; Tosaka, Masatoshi; Huneau, Bertrand; Verron, Erwan; Poompradub, Sirilux; Senoo, Kazunobu;, Dominating Factor of Strain-induced Crystallization in Natural Rubber Polymer 76, 230-236 (2015)
  5. Tien, Nguyen-Dung; Nishikawa, Yukihiro; Hashimoto, Masato; Tosaka, Masatoshi; Sasaki, Sono; Sakurai, Shinichi, Three-dimensional analysis of spherulite morphology in poly(oxyethylene) ans its blends with amorphous poly(d,l-lacic acid) using X-ray computerized tomography Polymer J. 47, 37-44 (2015)
  6. Hirao, T.; Tosaka, M.; Yamago, S.; Haino, T., Supramolecular Fullerene Polymers and Networks Directed by Molecular Recognition between Calix[5]arene and C60 Chem. Eur. J. 20, 16138-16146 (2014)
  7. 登阪雅聡, 架橋ゴムの伸長結晶化 高分子論文集 71(11), 493-500 (2014)
  8. 登阪雅聡, ゴムの伸長結晶化 Polyfile 51(6), 12-16 (2014)
  9. Kameda T, Nemoto T, Ogawa T, Tosaka M, Kurata H, Schaper A K, Evidence of α-helical coiled coils and β-sheets in hornet silk J. Struct. Biol. 185, 303-308 (2014)
  10. Tosaka M, Noda M, Ito K, Senoo K, Aoyama K, Ohta N, Strain- and Temperature-induced Polymorphism of Poly(dimethyl- siloxane) Colloid Polym. Sci., 291, 2719-2724 (2013)
  11. 登阪雅聡, 高分子結晶粒界の高分解能TEM観察 日本接着学会誌 49, 381-388 (2013)
  12. Asakawa H, Nishida K, Kanaya T, Tosaka M, Giant single crystal of isotactic polypropylene showing near-equilibrium melting temperature Polymer J. 45, 287–292 (2013)
  13. 登阪雅聡, 大きな歪みを与えられた高分子ネットワークの結晶化 繊維学会誌 69(3), P-81-P-87 (2013)
  14. 登阪雅聡, 妹尾政宣, プラズモン共鳴の異方性を示す金ナノ粒子/PDMSコンポジット 材料 62(1), 13-17 (2013)
  15. Tosaka M, Senoo K, Sato K, Noda M, Ohta N, Detection of Fast and Slow Crystallization Processes in Instantaneously-Strained Samples of cis-1,4-polyisoprene Polymer 53(3), 864–872 (2012)
  16. Nomoto Y, Matsunaga T, Sakai T, Tosaka M, Shibayama M, Structure and physical properties of dried Tetra-PEG gel Polymer 52, 4123-4128 (2011)
  17. Tosaka M, Toki S, Che J, Rong L, Hsiao B S, Development of internal fine structure in stretched rubber vulcanizates J. Polym. Sci. Part B: Polym. Phys. 49(16), 1157-1162 (2011)
  18. 登阪雅聡, 架橋ゴムの伸長による分子配向と結晶化および応力緩和 日本ゴム協会誌 84(3), 81-85 (2011)
  19. 登阪雅聡, 市田順寛, 中沖隆彦, 高分子配向薄膜を被覆した流路による金ナノ粒子チェーンの形成 材料 60(1), 47-50 (2011)
  20. Tosaka M, "Chapter 17 Morphology of Strain-Induced Crystals in Vulcanized Natural Rubber" in "Rubber: Types, Properties and Uses", Gabriel A. Popa Ed., Nova Science Publishers, Inc., pp.563-574 (2011)
  21. Tosaka M, Kohjiya S, Ikeda Y, Toki S, Hsiao B S, Molecular orientation and stress relaxation during strain-induced crystallization of vulcanized natural rubber Polym. J. 42, 474-481 (2010)
  22. Tosaka M, Yamaguchi K, Tsuji M, Latent orientation in the skin layer of electrospun isotactic polystyrene ultrafine fibers Polymer 51, 547-553 (2010)
  23. Tosaka M, Birefringence Study on Molecular Orientation of Natural Rubber During Strain-Induced Crystallization 高分子 58, 726 (2009)
  24. Tosaka M, A Route for the Thermodynamic Description of Strain-Induced Crystallization in Sulfur-Cured Natural Rubber Macromolecules 42, 6166-6174 (2009).
  25. 登阪雅聡, 村地優樹, 辻正樹 , 配向ポリテトラフルオロエチレン基板を用いたナノ粒子チェーンの自己組織化 材料 58(1), 41-45 (2009).
  26. 登阪雅聡, 古谷昌大, 辻正樹, 池田裕子, 粷谷信三, Dhirayos Wititsuwannakul, Rapepun Wititsuwannakul, 永山國昭, Radostin Danev, 新鮮なラテックスから分別された天然ゴムの伸長結晶化 材料 58(1), 5-10 (2009)
  27. Ikeda Y, Yasuda Y, Hijikata K, Tosaka M, Kohjiya S, Comparative Study on Strain-Induced Crystallization Behavior of Peroxide-Crosslinked and Sulfur-Crosslinked Natural Rubber Macromolecules 41(15), 5876-5884 (2008)
  28. Tosaka M, Strain-Induced Crystallization of Crosslinked Natural Rubber As Revealed by X-ray Diffraction Using Synchrotron Radiation Polymer J. 39(12), 1207-1220 (2007).
  29. Ikeda Y, Kato A, Shimanuki J, Kohjiya S, Tosaka M, Poompradub S, Toki S, Hsiao B S, Nano-Structural Elucidation In Carbon Black Loaded NR Vulcanizate By 3D-TEM And In Situ WAXD Measurements Rubber Chem. Technol. 80 (2), 251-264 (2007)
  30. Kohjiya S, Tosaka M, Furutani M, Ikeda Y, Toki S, Hsiao B S, Role of Stearic Acid in the Strain-Induced Crystallization of Crosslinked Natural Rubber and Synthetic cis-1,4-Polyisoprene Polymer 48(13), 3801-3808 (2007)
  31. Tosaka M, Senoo K, Kohjiya S, Ikeda Y, Crystallization of Stretched Network Chains in Cross-Linked Natural Rubber J. Appl. Phys 101, [84909-1]-[84909-8] (2007)
  32. Ikeda Y, Yasuda Y, Makino S, Yamamoto S, Tosaka M, Senoo K, Kohjiya S, Strain-induced crystallization of peroxide-crosslinked natural rubber Polymer 48(5), 1171-1175 (2007)
  33. Tosaka M, Tsuji M, Kohjiya S, Nagayama K, Self-Assembly of Nano-Sized Arrays on Highly Oriented Thin Films of Poly(tetrafluoroethylene) Mater. Sci. Forum 539-543, 3525-3527 (2007)
  34. Toki S, Hsiao B S, Kohjiya S, Tosaka M, Tsou A H, Datta S, Synchrotron X-Ray Studies of Vulcanized Rubbers and Thermoplastic Elastomers Rubber Chem. Technol. 79(3), 460-488 (2006)
  35. Tosaka M, Kawakami D, Senoo K, Kohjiya S, Ikeda Y, Toki S, ,Hsiao BS, Crystallization and stress relaxation in highly-stretched samples of natural rubber and its synthetic analogue. Macromolecules 39(15), 5100-5105 (2006)
  36. 登阪雅聡, こうじ谷信三, スマートナノコンポジットとしての天然ゴム 未来材料 6(3), 36-41 (2006)
  37. Tosaka M, Tsuji M, Ogawa T, Kitano H, Nakano K, Kohjiya S, Danev R, Nagayama K, Self-assembly of nano-sized arrays on highly oriented thin films of poly(tetrafluoroethylene) Polymer 47(4), 951-955 (2006)
  38. Tosaka M, Danev R, Nagayama K, Application of Phase Contrast Transmission Microscopic Methods to Polymer Materials Macromolecules 38(19), 7884-7886 (2005)
  39. Kojima M, Tosaka M, Funami E, Nitta K, Ohshima M, Kohjiya S, Phase behavior of crosslinked polyisoprene rubber and supercritical carbon dioxide J. Supercrit. Fluids 35(3), 175-181 (2005)
  40. Toki S, Sics I,Hsiao B S, Tosaka M, Poompradub S, Ikeda Y, Kohjiya S, Probing the Nature of Strain-Induced Crystallization in Polyisoprene Rubber by Combined Thermomechanical and In Situ X-ray Diffraction Techniques Macromolecules 38 (16), 7064-7073 (2005).
  41. Tosaka M, Murakami S, Poompradub S, Kohjiya S, Ikeda Y, Toki S, Sics I, Hsiao B S, Orientation and crystallization of natural rubber network as revealed by WAXD using synchrotron radiation National Synchrotron Light Source 2004 Activity Report, p. 2-92 - 2-93 (2005).
  42. 登阪雅聡(分担執筆), 高分子辞典 第3版 高分子学会編, 朝倉書店 (2005)
  43. こうじ谷信三, 登阪雅聡, 古谷昌大, S. Poompradub, 池田裕子, スマートin-situナノコンポジット:天然ゴムの伸長結晶化 日本化学繊維研究所講演集 62, 53-65 (2005)
  44. 古谷昌大, 登阪雅聡, こうじ谷信三, 池田裕子, 架橋天然ゴムの伸長結晶化における非ゴム成分、特にステアリン酸の効果について 接着 49, 202-207 (2005)
  45. Poompradub S, Tosaka M, Kohjiya S, Ikeda Y, Toki S, Sics I, Hsiao B S, Mechanism of strain-induced crystallization in filled and unfilled natural rubber vulcanizates J. Appl. Phys. 97, 103529-1 - 103529-9 (2005).
  46. Kojima M, Tosaka M, Ikeda Y, Kohjiya S, Devulcanization of Carbon Black Filled Natural Rubber by using Supercritical Carbon Dioxide J. Appl. Polym. Sci. 95, 137-143 (2005)
  47. Hirano K, Suzuki K, Nakano K, Tosaka M, Phase Separation Structure in the Polymer Blend of Fluorocarbon Elastomer and Hydrogenated Nitrile Rubber J. Appl. Polym. Sci. 95, 149-156 (2005)
  48. Tosaka M, Kohjiya S, Murakami S, Poompradub S, Ikeda Y, Toki S, Sics I, Hsiao B, Effect of network-chain length on strain-induced crystallization of NR and IR vulcanizates Rubber Chem. Technol. 77, 711-723 (2004)
  49. Toki S, Sics I, Ran S, Liu L, Hsiao B S, Murakami S, Tosaka M, Kohjiya S, Poompradub S, Ikeda Y, Tsou A H, Strain-induced molecular orientation and crystallization in natural and synthetic rubbers under uniaxial deformation by in-situ synchrotron X-ray study Rubber Chem. Technol. 37, 317-335 (2004).
  50. Tosaka M, Murakami S, Poompradub S, Kohjiya S, Ikeda Y, Toki S, Sics I, Hsiao B S, Orientation and crystallization of natural rubber network as revealed by WAXD using synchrotron radiation Macromolecules 37, 3299-3309 (2004).
  51. Toki S, Sics I, Hsiao B, Murakami S, Tosaka M, Poompradub S, Kohjiya S, Ikeda Y, Structural Developments in Synthetic Rubbers during Uniaxial Deformation by In Situ Synchrotron X-Ray Diffraction J. Polym. Sci., Part B: Polym. Phys. 42, 956-964 (2004)
  52. Poompradub S, Tosaka M, Kohjiya S, Ikeda Y, Toki S, Sics I, Hsiao B, Lattice Deformation of Strain-induced Crystallites in Carbon-filled Natural Rubber Chem. Lett. 33, 220-221 (2004).
  53. Kojima M, Tosaka M, Ikeda Y, Chemical recycling of sulfur-cured natural rubber using supercritical carbon dioxide Green Chem. 6, 84-89 (2004).
  54. 粷谷信三, 村上昌三, 登阪雅聡, Poompradub S, 土岐重之, Hsiao B H, 天然ゴムの伸長結晶化について 日本化学繊維研究所講演集, 60, 43-48 (2003).
  55. Udal'tsov A V, Tosaka M, Kaupp G, Microscopy of Large-Scale Porphyrin Aggregates Formed from Protonated TPP Dimers in Water-Organic Solutions J. Mol. Struct. 660, 15-23 (2003).
  56. Kojima M, Ogawa K, Mizoshima H, Tosaka M, Kohjiya S, Ikeda Y, Devulcanization of Sulfur-Cured Isoprene Rubber in Supercritical Carbon Dioxide Rubber Chem. Technol. 76, 957-968 (2003).
  57. Murakami K, Iio S, Ikeda Y, Ito H, Tosaka M, Kohjiya S, Effect of silane-coupling agent on natural rubber filled with silica generated in situ J. Mater. Sci. 38, 1447-1455 (2003)
  58. Tosaka M, Endo Y, Tsuji M, Kohjiya S, Stacking Faults and Growth of Syndiotactic Polypropylene Crystals J. Macromol. Sci., Phis. B42, 559-567 (2003)
  59. Bedia E, Paglicawan M, Bernas C, Bernardo S, Tosaka M, Kohjiya S, Natural weathering of polypropylene in a tropical zone J. Appl. Polym. Sci. 87, 931-938 (2003)
  60. Tosaka M, Kaupp G, Nanoindentation of Uniaxially Oriented Poly(tetrafluoroethylene) Thin Film Kobunshi Ronbunshu 59, 665-668 (2002)
  61. Bedia E, Tsuji M, Tosaka M, Ohara M, Kohjiya S, Morphologies of melt-crystallized thin films of nylon-6, nylon-6,6, and their blends as revealed by transmission electron microscopy J. Macromol. Sci., Phis. B40, 1079-1096 (2001)
  62. Tosaka M, Endo Y, Murakami S, Tsuji M, Kohjiya S, Ogawa T, Isoda S, High-Resolution Electron Microscopy of Lamellar Crystals of Syndiotacitc Polypropylene Sen-i Gakkaishi 57, 244-246 (2001)
  63. Tosaka M, Endo Y, Murakami S, Tsuji M, Kohjiya S, Quantitative Analysis of Stacking Faults in Lamellar Crystals of Syndiotactic Polypropylene Grown from the Melt Sen-i Gakkaishi 57, 207-211 (2001)
  64. Senoo K, Endo K, Tosaka M, Murakami S, Kohjiya S, Polymorphic behavior of syndiotactic polystyrene-based graft copolymers with polystyrene and polyisoprene side chains Macromolecules 34, 1267-1273 (2001)
  65. Shimizu T, Tosaka M, Tsuji M, Kohjiya S, TEM Observation of Natural Rubber Thin Films Crystallized under Molecular Orientation Rubber Chem. Technol. 73, 926-936 (2000)
  66. Tosaka M, Kamijo T, Tsuji M, Kohjiya S, Ogawa T, Isoda S, Kobayashi T, High-Resolution Transmission Electron Microscopy of Crystal Transformation in Solution-Grown Lamellae of Isotactic Polybutene-1 Macromolecules 33, 9666-9672 (2000)
  67. Shimizu T, Tosaka M, Tsuji M, Kohjiya S, In situ TEM observation of natural rubber thin films crystallized under molecular orientation J. Soc. Rubber Ind., Jpn. 73, 274-276 (2000)
  68. Senoo K, Endo K, Murakami S, Tosaka M, Crystallization of Newly Synthesized Syndiotactic Graft Copolymers Chem. Let. , 278-279 (2000)
  69. Tosaka M, Hamada N, Yamakawa M, Tsuji M, Kohjiya S, Molecular Packing in the New Unit Cell of Poly(p-hydroxybenzoic acid) Whisker Crystal Comput. Theor. Polym. Sci. 10, 355-364 (2000)
  70. Tosaka M, Yamakawa M, Tsuji M, Murakami S, Kohjiya S, Structural Studies on Polymer Whiskers by Transmission Electron Microscopy. II. Unit Cell of Poly(p-hydroxybenzoic acid) Whisker Crystal at Room Temperature. J. Polym. Sci., Part B: Polym. Phys. 37, 2456-2462 (1999)
  71. Tosaka M, Yamakawa M, Tsuji M, Kohjiya S, Ogawa T, Isoda S, Kobayashi T, Structural Studies on Polymer Whiskers by Transmission Electron Microscopy. I. High-resolution Observation Microsc. Res. Tech. 46, 325-333 (1999)
  72. Tosaka M, High-resolution Transmission Electron Microscopy of Crystalline Polymers Rec. Res. Develop. Macromol. Res. 4, 45-56 (1999)
  73. Tosaka M, Tsuji M, Kohjiya S, Cartier L, Lotz B, Crystallization of Syndiotactic Polystyrene in β-form. 4: Crystal Structure of Melt-grown Modification Macromolecules 32, 4905-4911 (1999)
  74. Tosaka M, Tsuji M, Kohjiya S, High-resolution Transmission Electron Microscopy of Polymer Crystals Mat. Sci. Res. Int. 4, 79-85 (1998)
  75. Tosaka M, Tsuji M, Cartier L, Lotz B, Kohjiya S, Ogawa T, Isoda S, Kobayashi T, High-resolution TEM of the melt-crystallized modification of syndiotactic polystyrene Polymer 39, 5273-5275 (1998)
  76. Tsuji M, Tosaka M, Kohjiya S, Polymer crystals observed by high-resolution electron microscopy Ann. Rep. Res. Inst. Chem. Fiber, Jpn. 54, 67-74 (1997)
  77. Tosaka M, Hamada N, Tsuji M, Kohjiya S, Crystallization of Syndiotactic Polystyrene in β-form. 3: Energetic Analysis of the Incorporation Mechanism of Stacking Faults into the Crystal. Macromolecules 30, 6592-6596 (1997)
  78. Hamada N, Tosaka M, Tsuji M, Kohjiya S, Katayama K, Crystallization of Syndiotactic Polystyrene in β-form. 2: Quantification of Stacking Faults in the Solution-Grown Single Crystals Macromolecules 30, 6888-6892 (1997)
  79. Fujita M, Hamada N, Tosaka M, Tsuji M, Kohjiya S, A TEM Study on Polyoxymethylene Rod-like Crystals Grown Epitaxially on NaCl J. Macromol. Sci., Phis. B36, 681-687 (1997)
  80. Tosaka M, Hamada N, Tsuji M, Kohjiya S, Ogawa T, Isoda S, Kobayashi T, Crystallization of Syndiotactic Polystyrene in β-form. 1. Positional Identification of Stacking Faults in the Solution Grown Single Crystals. Macromolecules 30, 4132-4136 (1997)
  81. Tosaka M, Epitaxial growth of polymers on the friction-transfered oriented thin film Kaigai Kohbunshi Kenkyu 42, 9-10 (1996)
  82. Tsuji M, Okihara T, Tosaka M, Kawaguchi A, Katayama K, Stacking Faults in Single Crystals of Syndiotactic Polystyrene MSA Bull. 23, 57-65 (1993)
  83. Tsuji M, Tosaka M, Kawaguchi A, Katayama K, Iwatsuki M, High-resolution Images of Uniaxially Oriented Thin Films of Polyethylene and Poly(4-methyl-1-pentene) with a Superconducting Cryo-TEM Sen-i Gakkaishi 48, 384-388 (1992)
  84. Tsuji M, Tosaka M, Kawaguchi A, Katayama K, Iwatsuki M, High-resolution Observation of Polymer Single Crystals with a Superconducting Cryo-TEM Bull. Inst. Chem. Res., Kyoto Univ. 69, 117-126 (1991)


Update: Sep 01,2017