Faculty Information, Institute for Chemical Research, Kyoto University   [ English | Japanese ]


SASAMORI, Takahiro

Division of Synthetic Chemistry - Organoelement Chemistry -
Associate Professor
Doctor Science
URL:http://boc.kuicr.kyoto-u.ac.jp/~sasamori/index_engl.html
E-mail: sasamori@boc.kuicr.kyoto-u.ac.jp
Tel: 0774-38-3202
Fax: 0774-38-3209
Academic career
    2002.3: Graduated from Dr. Course, Kyushu University
    2002.3: Dr. Sc., Kyushu University
    2002.4: Postdoctoral Fellow at Institute for Chemical Research, Kyoto University
    2003.4: Assistant Professor at Institute for Chemical Research, Kyoto University
Research field
    Organoelement Chemistry, Organoheteroatom Chemistry, Organometallic Chemistry
Current research
  1. Synthesis of Novel Heavier Main Group Element Species by Taking Advantage of Kinetic Stabilization and the Elucidation of Their Properties
Selected publications
  1. Tokitoh N, Arai Y, Sasamori T, Okazaki R, Nagase S, Uekusa H, Ohashi Y, A Unique Crystalline-State Reaction of an Overcrowded Distibene with Molecular Oxygen: The First Example of a Single Crystal to a Single Crystal Reaction with an External Reagent. J. Am. Chem. Soc., 1998, 120, 433-434.
  2. Tokitoh N, Sasamori T, Okazaki R, Synthesis of the First Stable Selenadistibirane and Its Molecular Structure. Chem. Lett., 1998, 1998, 725-726.
  3. Sasamori T, Takeda N, Tokitoh N, Synthesis of a Stable Stibabismuthene; The First Compound with an Antimony-Bismuth Double Bond. Chem. Commun., 2000, 1353-1354.
  4. Sasamori T, Arai Y, Takeda N, Okazaki R, Tokitoh N, The First Chemical Trapping of Stibinidene, a Monovalent Antimony Compound. Chem. Lett., 2001, 42-43.
  5. Tokitoh N, Arai Y, Sasamori T, Takeda N, Okazaki R, Formation of Antimony-Sulfur Double-Bond Compounds and Their Trapping with Nitrile Oxides Heteroatom Chem., 2001, 12, 244-249.
  6. Sasamori T, Takeda N, Fujio M, Kimura M, Nagase S, Tokitoh N, Synthesis and Structure of the First Stable Phosphabismuthene Angew. Chem. Int. Ed., 2002, 41, 139-141.
  7. Tokitoh N, Kishikawa K, Okazaki R, Sasamori T, Nakata N, Takeda N, Synthesis and Characterization of An Extremely Hindered Tetraaryl-substituted Digermene and Its Unique Properties in The Solid State and in Solution Polyhedron, 2002, 21, 563-577.
  8. Sasamori T, Arai Y, Takeda N, Okazaki R, Furukawa Y, Kimura M, Nagase S, Tokitoh N, Syntheses, Structure and Properties of Kinetically Stabilized Distibenes and Dibismuthenes, Novel Doubly Bonded Systems between Heavier Group 15 Elements. Bull. Chem. Soc. Jpn., 2002, 75, 661-675.
  9. Tokitoh N, Hatano K, Sasaki T, Sasamori T, Takeda N, Takagi N, Nagase S, Synthesis and Isolation of the First Germacyclopropabenzene: A Study to Elucidate the Intrinsic Factor for the Ring Deformation of Cyclopropabenzene Skeletons Organometallics, 2002, 21, 4309-4311.
  10. Tokitoh N, Suzuki H, Takeda N, Kajiwara T, Sasamori T, Okazaki R, Stable 2H-azasilirene and 2H-phosphasilirene: Addition Reaction of an overcrowded silylene to a nitrile and phosphaalkyne Silicon Chem., 2002, 1, 313-319.
  11. Tajima T, Hatano K, Sasaki T, Sasamori T, Takeda N, Tokitoh N, The First Examples of Stable Benzenes Fused with Two Three-membered Rings: Synthesis and Structures of the Two Stereoisomers of Bis(silacyclopropa)benzenes Chem. Lett., 2003, 32, 220-221.
  12. Sasamori T, Takeda N, Tokitoh N, Synthesis and Reactions of New Diphosphenes Bearing Extremely Bulky Substituents J. Phys. Org. Chem., 2003, 16, 450-462.
  13. Tajima T, Hatano K, Sasaki T, Sasamori T, Takeda N, Tokitoh N, Takagi N, Nagase S, Syntheses and structures of silicon analogues of cyclopropabenzenes J. Organomet. Chem., 2003, 686, 118-126.
  14. Sasamori T, Mieda E., Takeda N., Tokitoh N., Reaction of an Overcrowded Distibene with Elemental Sulfur and Crystallographic Analysis of the Sulfurization Products Chem. Lett., 2004, 33, 104-105.
  15. Tajima T, Sasaki T, Sasamori T, Takeda N, Tokitoh N, Thermal Reactions of an Overcrowded Germacyclopropabenzene with Group 6 Metal Hexacarbonyl Complexes [M(CO)6](M = Cr, Mo, and W): a Novel Mode of CO Insertion Leading to the Formation of Cyclic Germoxycarbene Metal Complexes Chem. Commun., 2004, 402-403.
  16. Mizuhata Y., Takeda N., Sasamori T. and Tokitoh N., Generation of 1,6-Disilahexapentaene in the Reduction of an Overcrowded Bis(bromodiaryl)butadiyne Leading to the Unexpected Formation of 2-Allenyl-1-benzosilole Chem. Lett., 2004, 33, 420-421.
  17. Kajiwara T., Takeda N., Sasamori T. and Tokitoh N., Insertion of an Overcrowded Silylene into Hydro- and Haloboranes: A Novel Synthesis of Silylborane Derivatives and Their Properties Organometallics, 2004, 23, 4723-4734.
  18. Kajiwara T., Takeda N., Sasamori T. and Tokitoh N., Unprecedented Insertion Reaction of a Silylene into a B-B Bond and Generation of a Novel Borylsilyl Anion by Boron-Metal Exchange Reaction of the Resultant Diborylsilane Chem. Commun. 2004, 2218-2219.
  19. Nagahora N., Sasamori T., Takeda N. and Tokitoh N., A Kinetically Stabilized Ferrocenyl Diphosphene: Synthesis, Structure, Properties, and Redox Behavior Chem. Eur. J. 2004, 10, 6146-6151.
  20. Sasamori T., Mieda E., Nagahora N., Takeda N., Takagi N., Nagase S. and Tokitoh N., Systematic Studies on Redox Behavior of Homonuclear Double-bond Compounds of Heavier Group 15 Elements Chem. Lett. 2005, 34, 166-167.
  21. Sasamori T., Sasaki T., Takeda N. and Tokitoh N., Reactions of a Germacyclopropabenzene with Elemental Chalcogens: Syntheses and Structures of a Series of Stable 2H-Benzo[c][1,2]chalcogenagermetes Organometallics 2005, 24, 612-618.
  22. Tajima T., Sasaki T., Sasamori T., Takeda N. and Tokitoh N., Reactivities of Germacyclopropabenzene toward Some Transition Metal Carbonyl Complexes Appl. Organometal. Chem. 2005, 19, 570-577.
  23. Sasamori T., Mieda E., Takeda N. and Tokitoh N., Telluradistibirane and Telluradibismirane: Three-Membered Heterocycles of Heavier Main Group Elements Angew. Chem. Int. Ed. 2005, 44, 3717-3720.
  24. Shinohara A., Takeda N., Sasamori T. and Tokitoh N., Synthesis of Kinetically Stabilized 1-Silanaphthalenes and Their Properties Bull. Chem. Soc. Jpn. 2005, 78, 977-987.
  25. Nagahora N., Sasamori T., Takeda N. and Tokitoh N., Synthesis and Structure of a Stable 1,3-Dihydrotriphosphane and Its Thermal Decomposition Leading to the Formation of the Corresponding Phosphine and Diphosphene Organometallics 2005, 24, 3074-3080.
  26. Sasamori T., Sugiyama Y., Takeda N. and Tokitoh N., Structure and Properties of an Overcrowded 1,2-Dibromodigermene Organometallics 2005, 24, 3309-3314.
  27. Takeda N., Shimizu D., Sasamori T. and Tokitoh N., Dichloro[1,2-bis(phenylsulfanyl)benzene]palladium(II), Dichloro[1,2-bis(phenylsulfanyl)benzene]palladium(II) Acta Cryst. E 2005, E61, m1408-m1410.
  28. Mizuhata Y., Takeda N., Sasamori T. and Tokitoh N., Generation of 9-Stannaphenanthrene and Its Reactivities Chem. Lett. 2005, 34, 1088-1089.
  29. Tajima T., Takeda N., Sasamori T. and Tokitoh N., Generation and Reactions of Overcrowded Diaryldilithiostannane and Diaryldipotassiostannane Eur. J. Inorg. Chem. 2005, 4291-4300.

Update: Aug 03,2012