Faculty Information, Institute for Chemical Research, Kyoto University   [ English | Japanese ]


NAKAJIMA, Yumiko

Research Center for Elements Science - Organotransition Metal Chemistry -
Assistant Professor

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Academic career
Research field
    Current research
    Selected publications
    1. H. Kameo, Y. Nakajima, H. Suzuki, Drastic Acceleration of Phosphine/Phosphate Incorporation into a Tetrahydrido Ruthenium/Osmium Complex, and One-way Ruthenium to Osmium Migration of a Phosphorus Ligand Angew. Chem. Int. Ed. 47, 10159-10162 (2008)
    2. Yumiko Nakajima, Zhaomin Hou, Rare-earth Metal/Platinum Heterobinuclear Complexes Containing Reactive Ln-alkyl groups (Ln = Y, Lu): Synthesis, Structural Characterization and Reactivity Organometallics 28, 6861-6870 (2009)
    3. Kameo H, Shima T, Nakajima Y, Suzuki H , Synthesis of Heterometallic Trinuclear Polyhydrido Clusters Containing Ruthenium and Osmium and Their Electronic and Structural Deviation from Homometallic Systems organometallics 28, 2535-2545 (2009).
    4. Wakioka M, Nakajima Y, Ozawa F , Mechanism of C-P Reductive Elimination from trans-[Pd(CH=CHPh)Br(PMePh2)2] organometallics 28, 2527-2534 (2009).
    5. Nakajima Y, Suzuki H, Nitrogen-Nitrogen Bond Cleavage of Hydrazine Derivatives by Trinuclear Pentahydride Complex of Ruthenium, (Cp’Ru)3(μ-H)3(μ3-H)2 (Cp’ = C5Me5) Organometallics 22, 959-969 (2003).
    6. Nakajima Y, Inagaki A, Suzuki H, Reductive Cleavage of the N-N Bond of Hydrazine Induced by a Cationic Trinuclear Ruthenium Hexahydride Complex, [(Cp’Ru)3(μ-H)6]X (Cp’ = C5Me5; X = 1/2(SO4), BF4, PF6) Organometallics 23, 4040-4046 (2004).
    7. Nakajima Y, Suzuki H, Nitrogen-Nitrogen Double Bond Cleavage of Azobenzene by a Triruthenium　Pentahydrido Complex, (Cp’Ru)3(μ3-H)2(μ-H)3 (Cp’ = C5Me5), and Catalytic Hydrogenation of Azobenzene and 1,2-Diphenylhydrazine Organometallics 24, 1860-1866 (2005).
    8. Nakajima Y, Kameo H, Suzuki H, Cleavage of Nitrogen-Hydrogen Bonds of Ammonia Induced by Triruthenium Polyhydrido Clusters Angew. Chem. Int. Ed. 45, 950-952 (2006).
    9. Kramer M U, Robert D, Nakajima Y, Englert U, Spaniol T P, Okuda J , Alkyl Abstraction from a Trialkylyttrium Complex [YR3(thf)2] (R = CH2SiMe3) Using a Group-13 Element Lewis Acid ER3 (E = B, Al, Ga, In) – Structural Characterization of the Ion Pair [YR2(thf)4]+[GaR4]- and ER3 (E = B, Al, Ga). Eur. J. Inorg. Chem. 665-679 (2007).
    10. Nakajima Y, Okuda J , Reactivity of Monocationic Bis(alkyl) and Dicationic Mono(alkyl) Yttrium Complexes toward Ketones and Carbon Dioxide Organometallics 26, 1270-1278 (2007).
    11. Kameo H, Nakajima Y, Suzuki H, Hydrogenation of a Trinuclear μ3-Imido Complex of Ruthenium: Homolytic or Heterolytic H-H Bond Cleavage? Eur. J. Inorg. Chem. 1793-1798 (2007).
    12. Nakajima Y, Nakatani M, Hayashi K, Shiraishi Y, Takita R, Okazaki M, Ozawa F, Synthesis and Structures of Platinum Diphenylacetylene and Dithiolate Complexes bearing Diphosphinidenecyclobutene Ligands (DPCB-Y) New J. Chem. 34, 1713-1722 ((2010))
    13. Nakajima Y, Nakao Y, Sakaki S, Tamada Y, Ono T, Ozawa F, Electronic Structure of Four-coordinate Iron(I) Complex Supported by a Bis(phosphaethenyl)pyridine Ligand J. Am. Chem. Soc. 132, 9934-9936 ((2010))
    14. Hayashi K, Nakajima Y, Ozawa F, Kawabata T, Axially Chiral Anilido-Aldimine Aluminum Complexes with a Pseudobinaphthyl Skeleton Chem. Lett. 39, 643-645 ((2010))
    15. Asai K, Konishi G, Nakajima Y, Kawauchi S, Ozawa F, Mizuno K, Enhanced Absorption and Fluorescence Efficiency of Silylethynyl-Functionalized Oligothiophenes and Thieno[3,2-b]thiophene J. Organomet. Chem. 696, 1266-1271 (2011)
    16. Nakajima, Y.; Shiraishi, Y.; Tsuchimoto, T.; Ozawa, F., Synthesis and Coordination Behavior of CuI Bis(phosphaethenyl)pyridine Complexes Chem. Commun. 47, 6332-6334 (2011)
    17. Kameo, H.; Nakajima, Y.; Namura, K.; Suzuki, H. , Heterometallic Effects in Nitrogen–Hydrogen Bond Cleavage by Trinuclear Mixed-Metal Polyhydrido Clusters Containing Ruthenium and Osmium in press

    Update: Apr 02,2012