Faculty Information, Institute for Chemical Research, Kyoto University   [ English | Japanese ]


MIZUHATA, Yoshiyuki

Division of Synthetic Chemistry - Organoelement Chemistry -
（Laboratory in the Kyoto University）
Assistant Professor
Doctor Science
URL:http://boc.kuicr.kyoto-u.ac.jp/~mizu/index_E.html
E-mail: mizu@boc.kuicr.kyoto-u.ac.jp
Tel: 0774-38-3203
Fax: 0774-38-3209
Academic career
    2006. 3 Graduated from Dr. Course, Kyoto University
    2006. 3 Dr. Sc., Kyoto University
    2006. 4 Postdoctoral Fellow at Institute for Chemical Research, Kyoto University
    2006.11 Assistant Professor at Institute for Chemical Research, Kyoto University
Research field
    Organoelement Chemistry, Organometallic Chemistry, Organoheteroatom Chemistry
Current research
  1. Synthesis of Novel Heavier Main Group Element Species by Taking Advantage of Kinetic Stabilization and the Elucidation of Their Properties
Selected publications
  1. Mizuhata Y, Tokitoh N , Chemistry of Aromatic Compounds Containing a Heavier Group 14 Elements J. Synth. Org. Chem., Jpn. 69, 691-704 (2011).
  2. Mizuhata Y, Sasamori T, Tokitoh N, Stable heavier carbene analogues. Chem. Rev. 109, 3479-3511 (2009).  [pubmed]
  3. Mizuhata Y, Tokitoh N, Stannenes, distannenes, and stannynes. in "Tin Chemistry: Fundamentals, Applications and Frontiers", ed. by Gielen M, Davies A G, Pannell K, Tiekink E, John Wiley & Sons, Chichester, pp. 177-200.
  4. Han JS, Sasamori T, Mizuhata Y, Tokitoh N, Evidence for LiBr-Assisted Generation of a Silylene from a 1,2-Diaryl-1,2-dibromodisilene. Chem Asian J (2011)  [pubmed]
  5. Mizuhata Y, Sato T, Tokitoh N, Reactions of an Overcrowded Silylene with Pyridines: Formation of a Novel 2H-1,2-Azasilepine and Its Further Cycloaddition Heterocycles 84, 413-418 (2011).
  6. Tokitoh N, Inamura K, Mizuhata Y, New Aspects in the Coordination Chemistry of Ge- and Sn-Containing Metallaaromatic Compounds Phosphorus, Sulfur, and Silicon and the Related Elements 186, 1323-1325 (2011).
  7. Mizuhata Y, Tokitoh N, The First Observation of 1J(Sn–C) Coupling Constants in Tin–carbon Double-bond Compounds Appl. Organomet. Chem. 24, 902-906 (2010).
  8. Mizuhata Y, Noda N, Tokitoh N, Generation of Stannabenzenes and Their Properties Organometallics 29, 4781-4784 (2010).
  9. Han JS, Sasamori T, Mizuhata Y, Tokitoh N., Reactivity of an aryl-substituted silicon-silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes. Dalton Trans. 39, 9238-9240 (2010).  [pubmed]
  10. Sato T, Mizuhata Y, Tokitoh N., 1,2-Dialkynyldisilenes: silicon analogues of (E)-enediyne. Chem. Commun. 46, 4402-4404 (2010).  [pubmed]
  11. Tanabe Y, Mizuhata Y, Tokitoh N, Novel Silacyclohexadienyl Chromium and Iron Complexes Bearing a Bulky Substituent on the Central Silicon Atom. Pure Appl. Chem. 82, 879-890 (2010).
  12. Han JS, Sasamori T, Mizuhata Y, Tokitoh N , Reactivity of an aryl-substituted silicon-silicon triple bond: reactions of a 1,2-diaryldisilyne with alkenes J. Am. Chem. Soc. 132, 2546-2547 (2010).  [pubmed]
  13. Tanabe Y, Mizuhata Y, Tokitoh N, Synthesis and Structure of a Heavier Congener of Biphenyl: 1,1'-Disila-4,4'-biphenyl. Organometallics 29, 721-723 (2010).
  14. Mizuhata Y, Shinohara A, Tanabe Y, Tokitoh N, Cycloaddition Reactions of Kinetically Stabilized 9-Silaanthrancene with Polycyclic Aromatic Hydrocarbons. Chem. Eur. J. 15, 8405-8408 (2009).  [pubmed]
  15. Mizuhata Y, Tokitoh N, Reactions of a Kinetically Stabilized 2-Stannanaphthalene with Elemental Sulfur and Selenium: Synthesis of Novel Cyclic Chalcogenides Containing a Tin Atom. J. Sulf. Chem. 30, 385-392 (2009).
  16. Mizuhata Y, Inamura K, Tokitoh N, Reaction of 9-Germaphenanthrene with Dimethyl Acetylenedicarboxylate: Unexpected Formation of a 1,2-Oxagermolane Derivative. Heterocycles 77, 811-816 (2009).
  17. Tanabe T, Mizuhata Y, Takeda N, Tokitoh N, Syntheses and structures of overcrowded silanedichalcogenols and their applications to the syntheses of silanedichalcogenolato complexes. J. Organomet. Chem. 694, 353-365 (2009).
  18. Mizuhata Y, Sasamori T, Nagahora N, Watanabe Y, Furukawa Y, Tokitoh N, Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements. Dalton Trans. 4409-4418 (2008).  [pubmed]
  19. Tanabe Y, Mizuhata Y, Tokitoh N, Mechanistic investigation of the hydration reaction of [Cr(η6-silabenzene)(CO)3]: Hydrido(silacyclohexadienyl)chromium complex as an intermediate. Chem. Lett. 37, 720-721 (2008).
  20. Tanabe T, Mizuhata Y, Takeda N, Tokitoh N, Syntheses and structures of platinum siloxides bridged by a sulfur or selenium atom and a unique 1,3-aryl migration from silicon to platinum through the Si-O-Pt linkages. Organometallics 27, 2156-2158 (2008).
  21. Isobe T, Mizuhata Y, Tokitoh N, Acyclic Tetrachalcogenoether Ligands Tethered with Bulky Substituents: Their Syntheses and Coordination Chemistry. J. Organomet. Chem. 693, 1225-1232 (2008).
  22. Mizuhata Y, Tokitoh N, 9,9'-Dibromo-9,9'-bifluorene. Acta Cryst. E 64, 544 (2008).
  23. Mizuhata Y, Tokitoh N, (E)-N-{2-(9-Fluorenylidene)-3a,5,7-trimethyl-2H-indol-3-ylidene}-2,4,6-trimethylaniline. Acta Cryst. E 64, 493 (2008).
  24. Sasamori T, Inamura K, Hoshino W, Nakata N, Mizuhata Y, Watanabe Y, Furukawa Y, Tokitoh N, Synthesis and characterization of two isomers of 14π-electron germaaromatics: kinetically stabilized 9-germaanthracene and 9-germaphenanthrene. Organometallics 25, 3533-3536 (2006).
  25. Mizuhata Y, Sasamori T, Takeda N, Tokitoh N, A stable neutral stannaaromatic compound: synthesis, structure and complexation of a kinetically stabilized 2-stannanaphthalene. J. Am. Chem. Soc. 128, 1050-1051 (2006).  [pubmed]
  26. Mizuhata Y, Takeda N, Sasamori T, Tokitoh N, Synthesis and properties of a stable 6-stannapentafulvene. Chem. Commun. 5876-5878 (2005).  [pubmed]
  27. Mizuhata Y, Sasamori T, Takeda N, Tokitoh N, Generation of 9-stannaphenanthrene and its reactivities. Chem. Lett. 34, 1088-1089 (2005).
  28. Mizuhata Y, Takeda N, Tokitoh N, Reduction of bis(bromo(mesityl){2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}silyl)butadiyne with potassium graphite: unexpected formation of 2-allenyl-1-benzosilole. Phosphorus, Sulfur, and Silicon and the Related Elements 179, 947-948 (2004).
  29. Mizuhata Y, Takeda N, Sasamori T, Tokitoh N, Generation of 1,6-disilahexapentaene in the reduction of an overcrowded bis(bromodiaryl)butadiyne leading to the unexpected formation of 2-allenyl-1-benzosilole. Chem. Lett. 33, 420-421 (2004).
  30. Ogasawara M, Ueyama K, Nagano T, Mizuhata Y, Hayashi T, Palladium-catalyzed asymmetric synthesis of axially chiral (allenylmethyl)silanes and chirality transfer to stereogenic carbon centers in SE' reactions. Org. Lett. 5, 217-219 (2003).  [pubmed]

Update: Apr 02,2012