京都大学化学研究所研究者情報   [ English | Japanese ]


橋川 祥史(はしかわ よしふみ)

物質創製化学研究系 構造有機化学
((工学研究科物質エネルギー化学専攻 協力講座) 協力講座)
助教

URL:http://www.scl.kyoto-u.ac.jp/~kouzou/member/hasshi.html
E-mail: hashi@scl.kyoto-u.ac.jp
Tel: 0774-38-3174
Fax: 0774-38-3178
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研究・教育歴
    2010.3. 新居浜工業高等専門学校 生物応用化学科 卒業/準学士(工学)
    2010.4-2013.3. ㈱住化分析センター 愛媛事業所 安全工学研究室
    2012.2-2013.3. 住友化学㈱ 火災爆発体感研修 講師
    2015.3. 京都大学大学院 工学研究科 物質エネルギー化学専攻 修士課程 修了/修士(工学)
    2015.4-2017.3. 日本学術振興会特別研究員(DC1)
    2017.4- 京都大学化学研究所 助教
専門分野
    生物化学,安全工学,フラーレン化学,構造有機化学
主な研究テーマ
  1. 小分子内包フラーレンの合成と物性
  2. NMRを用いた弱い相互作用の評価
  3. 金属錯体の合成および遷移金属触媒を用いた反応開発
  4. 理論計算に基づく反応機構解析
主な論文・著書
  1. Guo-Zhu Zhu, Yuan Liu, Yoshifumi Hashikawa, Qian-Fan Zhang, Yasujiro Murata, Lai-Sheng Wang, Probing the Interaction between the Encapsulated Water Molecule and the Fullerene Cages in H2O@C60 and H2O@C59N. Chem. Sci. 2018, in press.
  2. Yoshifumi Hashikawa, Hidefumi Yasui, Kei Kurotobi, Yasujiro Murata, Synthesis and Properties of Open-Cage Fullerene C60 Derivatives: Impact of the Extended π-Conjugation. Mater. Chem. Front. 2018, 2, 206–213.
  3. Guo-Zhu Zhu, Yoshifumi Hashikawa, Yuan Liu, Qian-Fan Zhang, Ling Fung Cheung, Yasujiro Murata, Lai-Sheng Wang, High-Resolution Photoelectron Imaging of Cryogenically-Cooled C59N and (C59N)22– Azafullerene Anions. J. Phys. Chem. Lett. 2017, 8, 6220−6225.
  4. Yoshifumi Hashikawa, Yasujiro Murata, Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules. J. Am. Chem. Soc. 2017, 139, 18468–18471.
  5. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C60 Derivatives. J. Am. Chem. Soc. 2017, 139, 16350−16358.
  6. Masashi Ozaki, Yukie Katsuki, Jiewei Liu, Taketo Handa, Ryosuke Nishikubo, Shinya Yakumaru, Yoshifumi Hashikawa, Yasujiro Murata, Takashi Saito, Yuichi Shimakawa, Yoshihiko Kanemitsu, Akinori Saeki, Atsushi Wakamiya, Solvent-Coordinated Tin Halide Complexes as Purified Precursors for Tin-Based Perovskites. ACS Omega 2017, 2, 7016–7021.
  7. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Orientation of a Water Molecule: Effects on Electronic Nature of the C59N Cage. J. Org. Chem. 2017, 82, 4465–4469.
  8. Satoshi Kaneko, Yoshifumi Hashikawa, Shintaro Fujii, Yasujiro Murata, Manabu Kiguchi, Single Molecular Junction Study on H2O@C60: H2O is "Electrostatically Isolated". Chem. Phys. Chem. 2017, 18, 1229–1233.
  9. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Structural Modification of Open-Cage Fullerene C60 Derivatives Having a Small Molecule inside Their Cavities. Can. J. Chem. 2017, 95, 320–328.
  10. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η2-C60). Org. Lett. 2016, 18, 6348−6351.
  11. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization. Angew. Chem., Int. Ed. 2016, 55, 13109–13113.
  12. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Synthesis and Properties of Endohedral Aza[60]fullerenes: H2O@C59N and H2@C59N as Their Dimers and Monomers. J. Am. Chem. Soc. 2016, 138, 4096–4104.
  13. Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, Synthesis of Open-Cage Ketolactam Derivatives of Fullerene C60 Encapsulating a Hydrogen Molecule. Org. Lett. 2014, 16, 2970–2973.


Update: Jun 28,2018