京都大学化学研究所研究者情報   [ English | Japanese ]


岩本 貴寛(いわもと たかひろ)

元素科学国際研究センター 有機分子変換化学
(京都大学大学院工学研究科・物質エネルギー専攻 協力講座 協力講座 協力講座)
特定助教
博士(工学)
URL:
E-mail: iwamoto@scl.kyoto-u.ac.jp
Tel: 0774-38-3182
Fax: 0774-38-3186

研究・教育歴
    2009.3 京都大学工学部工業化学科 卒業
    2011.3 京都大学大学院工学研究科高分子化学専攻修士課程 修了
    2014.3 京都大学大学院工学研究科高分子化学専攻博士後期課程 修了
    2011.3-2014.3 日本学術振興会特別研究員DC1
専門分野
    有機合成化学、有機金属化学
主な研究テーマ
  1. 新規反応、新規触媒の開発
主な論文・著書
  1. Yoshida, R.; Isozaki, K.; Yokoi, T.; Yasuda, N.; Sadakane, K; Iwamoto, T.; Takaya, H.; Nakamura. M., ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide Org. Biomol. Chem. (2016)
  2. Agata, R.; Iwamoto, T.; Nakagawa, N.; Isozaki, K.; Hatakeyama, T.; Takaya, H.; Nakamura. M., Iron(III) Fluoride/N-Heterocyclic Carbene Catalyzed Cross Coupling between Deactivated Aryl Chlorides and Alkyl Grignard Reagents with or without -Hydrogens Synthesis 47, 1733-1740 (2015)
  3. Iwamoto, T.; Takaya, H.; Yamago, S., Structural Investigation of Cycloparaphenylene –Fullerene Supramolecular Complexes Using Synchrotron Radiation and Theoretical Calculation Nihon Kessho Gakkaishi 57, 239-244 (2015)
  4. Gallego, M.; Calbo, J.; Aragó, , J.; Krick Calderon, R. M.; Liquido, F. H.; Iwamoto, T.; Greene, A. K.; Jackson, E. A.; Pérez, E. M.; Ortí, E.; Guldi, D. M.; Scott, L. T.; Martín, N., Electron Transfer in a Supramolecular Associate of a Fullerene Fragment Angew. Chem. Int. Ed. 53, 7033-7037 (2014)(VIP, Cover picture)
  5. Takaya, H.; Nakajima, S.; Nakagawa, N.; Isozaki, K.; Iwamoto, T.; Imayoshi, R.; Gower, N. J.; Adak, L.; Hatakeyama, T.; Honma, T.; Takagaki, M.; Sunada, Y.; Nagashima, H.; Hashizume, D.; Takahashi, O.; Nakamura. M., Investigation of Organoiron Catalysis in Kumada–Tamao–Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy Bull. Chem. Soc. J. 20, 14403-14409 (2015)
  6. Kayahara, E; Qu, R.; Kojima, M.; Iwamoto, T.; Suzuki, T.; Yamago, S., Ligand-controlled Synthesis of [3]- and [4]Cyclo-9,9-dimethyl-2,7-fluorenes through Triangle- and Square-shaped Platinum Intermediates Chem. Eur. J. 21, 18939-18943 (2015)
  7. Fujistuka, M.; Tojo, S.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T., Radical Ions of Cyclopyrenylene: Comparison of Spectral Properties with Cycloparaphenylene. J. Phys. Chem. Part A 119, 4136-4141 (2015)
  8. Iwamoto, T.; Slanina, Z.; Mizorogi, N.; Guo, J.; Akasaka, T.; Nagase, S.; Takaya, H.; Yasuda, N.; Kato, T.; Yamago, S., Partial Charge Transfer in Shortest Possible Metallofullerene Peapod, La@C82⊂[11]Cycloparaphenylene. Chem. Eur. J. 20, 14403-14409 (2014)
  9. PeñaAlvarez, M.; Burrezo, P. M.; Iwamoto, T.; Qiu, L.; Kertesz, M.; Taravillo, M.; Baonza, V. G.; Navarrete, J. T. L.; Yamago, S.; Casado, J. , Chameleon-like Behaviour of Cyclo[n]paraphenylenes in Complexes with C70. On Their Impressive Electronic and Structural Adaptability as probed By Raman spectroscopy. Faraday Discuss. 173, 157-171 (2014)
  10. Fujitsuka, M.; Tojo, S.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T. , Radical Ions of Cycloparaphenylenes: Size-Dependence Contrary to the Neutral Molecules J. Phys. Chem. Lett. 5, 2302-2305 (2014)(Highlighted in ACS LiveSlides)
  11. Fujitsuka, M.; Lu, C.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T. , Properties of Triplet-Excited [n]Cycloparaphenylenes (n = 8–12): Excitation Energies Lower than Those of Linear Oligomers and Polymers J. Phys. Chem. A 118, 4527-4532 (2014)
  12. Alvarez, M. P.; Burrezo, P. M.; Kertesz, M.; Iwamoto, T.; Yamago, S.; Xia, J.; Jasti, R.; Navarrete, J. T. L.; Taravillo, M.; Baonza, V. G.; Casado, J. , Properties of Sizeable [n]Cycloparaphenylenes as Molecular Models of Single-Wall Carbon Nanotubes Elucidated by Raman Spectroscopy: Structural and Electron-Transfer Responses under Mechanical Stress Angew. Chem. Int. Ed. 53, 7033-7037 (2014)
  13. Iwamoto, T.; Kayahara, E.; Yasuda, N.; Suzuki, T.; Yamago, S., Synthesis, Characterization, and Properties of [4]Cyclo-2,7-pyrenylene: Effect of Cyclic Structure on the Electronic Properties of Pyrene Oligomers Angew. Chem. Int. Ed. 53, 6430-6434 (2014)
  14. Yamago, S.; Kayahara, E.; Iwamoto, T., Organoplatinum-Mediated Synthesis of Cyclic π-Conjugated Molecules: Towards a New Era of Three-Dimensional Aromatic Compounds Chem. Rec. 14, 84-100 (2014)
  15. Yamago, S.; Kayahara, E.; Iwamoto, T., New Organic Chemistry of Three-Dimensional π-Conjugated Compounds Journal of Synthetic Organic Chemistry, Japan. 72, 992-1005 (2014)
  16. Kayahara, E.; Iwamoto, T.; Takaya, H.; Suzuki, T.; Fujitsuka, M.; Majima, T.; Yasuda, N.; Matsuyama, N.; Seki, S.; Yamago, S., Synthesis and physical properties of a ball-like three-dimensional π-conjugated molecule Nature Commun. 4, 2694 (2013)(京都新聞(2013/10/30)、日経産業新聞(2013/10/30)、日刊工業新聞(2013/10/30)、朝日新聞(2013/11/28)、読売新聞(2014/1/13)に掲載)
  17. Iwamoto, T.; Watanabe, Y.; Takaya, H.; Haino, T.; Yasuda, N.; Yamago, S., Size- and Orientation-Selective Encapsulation of C70 by Cycloparaphenylenes Chem. Eur. J. 19, 14061-14068 (2013)(VIP, Inside Cover Picture, Highlighted by ChemViews Magazine)
  18. Kayahara, E.; Iwamoto, T.; Suzuki, T.; Yamago, S., Selective Synthesis of [6]-, [8]-, and [10]Cycloparaphenylenes Chem. Lett. 42, 621-623 (2013)
  19. Fujitsuka, M.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T., Enhancement of quinoidal character of smaller [n]cycloparaphenylenes probed by Raman spectroscopy ChemPhysChem. 14, 1570-1572 (2013)
  20. Fujitsuka, M.; Cho, D. W.; Iwamoto, T.; Yamago, S.; Majima, T., Size-Dependent Fluorescence Properties of [n]Cycloparaphenylenes (n =8 - 13), Hoop-Shaped π-Conjugated Molecules Phys. Chem. Chem. Phys. 14, 14585-14588 (2012)
  21. Iwamoto T, Watanabe Y, Sakamoto Y, Suzuki T, Yamago S., Selective and random syntheses of [n]cycloparaphenylenes (n=8-13) and size dependence of their electronic properties. J Am Chem Soc 133, 8354-61 (2011)  [pubmed]
  22. Iwamoto, T.; Watanabe, Y.; Sadahiro, T.; Haino, T.; Yamago, S., Size-Selective Encapsulation of C60 by [10]Cycloparaphenylene. Formation of the Shortest Fullerene-Peapod Angew. Chem. Int. Ed. 50, 8342-8344 (2011)  [pubmed]
  23. Yamago, S.; Watanabe, Y.; Iwamoto, T., Synthesis of [8]Cycloparaphenylene from a Square-Shaped Tetranuclear Platinum Complex Angew. Chem. Int. Ed. 49, 757 (2010)VIP, Inside Cover Picture, Highlighted by synfact, 日経工業新聞(2009/12/22)


Update: Jul 18,2017