京都大学化学研究所研究者情報   [ English | Japanese ]


竹内 勝彦(たけうち かつひこ)

元素科学国際研究センター 錯体触媒変換化学
助教
博士(理学)
URL:http://om.kuicr.kyoto-u.ac.jp/index.html
E-mail: ktakeuch@scl.kyoto-u.ac.jp
Tel: 0774-38-3029
Fax: 0774-38-3039

研究・教育歴
    2007.03 筑波大学第一学群自然学類化学専攻 卒業
    2009.03 筑波大学大学院数理物質科学研究科博士前期課程 修了
    2012.03 筑波大学大学院数理物質科学研究科博士後期課程 修了
    2012.03 博士(理学)取得(筑波大学)
    2012.04 トロント大学博士研究員(日本学術振興会 海外特別研究員)
    2013.08 京都大学化学研究所助教
専門分野
    有機金属化学
主な研究テーマ
  1. 後周期有機遷移金属錯体の合成・構造・反応性の解明
主な論文・著書
  1. Taguchi, H.; Sasaki, D.; Takeuchi, K.; Tsujimoto, S.; Matsuo, T.; Tanaka, H.; Yoshizawa, K.; Ozawa, F., Unsymmetrical PNP-Pincer Type Phosphaalkene Ligands Protected by a Fused-Ring Bulky Eind Group: Synthesis and Applications to Rh(I) and Ir(I) Complexes Organometallics 35, 1526-1533 (2016)
  2. Nakajima, Y.; Tsuchimoto, T.; Chang, Y.-H.; Takeuchi, K.; Ozawa, F., Reactions of [Cu(X)(BPEP-Ph)] (X = PF6, SbF6) with Silyl Compounds. Cooperative Bond Activation Involving Non-coordinating Anions Dalton Trans. 45, 2079-2084 (2016)
  3. Chang, Y-H.; Tanigawa, I.;Taguchi, H.; Takeuchi, K.; Ozawa, F., Iridium(I) Complexes Bearing a Noninnocent PNP-Pincer Type Phosphaalkene Ligand: Catalytic Application to Base-Free N-Alkylation of Amines with Alcohols Eur. J. Inorg. Chem. 2016, 754-760 (2016)
  4. Yung-Hung Chang, Katsuhiko Takeuchi, Masayuki Wakioka, Fumiyuki Ozawa , C–H Bond Cleavage of Acetonitrile by Iridium Complexes Bearing PNP-Pincer-Type Phosphaalkene Ligands Organometallics 34, 1957-1962 (2015)
  5. Hiro-omi Taguchi, Yung-Hung Chang, Katsuhiko Takeuchi, Fumiyuki Ozawa, Catalytic Synthesis of an Unsymmetrical PNP-Pincer-Type Phosphaalkene Ligand Organometallics 34, 1589-1596 (2015)
  6. Roman Dobrovetsky, Katsuhiko Takeuchi, Douglas W. Stephan, Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation Chem. Commun. 51, 2396-2398 (2015)
  7. Katsuhiko Takeuchi, Ataru Minami, Yumiko Nakajima, Fumiyuki Ozawa, Synthesis and Structures of Nickel Complexes with a PN-Chelate Phosphaalkene Ligand Organometallics 33, 5365-5370 (2014)
  8. Katsuhiko Takeuchi, Lindsay J. Hounjet, Douglas W. Stephan, Frustrated Lewis Pair Route to Hydrodesilylation of Silylphosphines Organometallics 32, 4469-4472 (2013)
  9. Katsuhiko Takeuchi, Douglas W. Stephan, Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2 Chem. Commun. 48, 11304-11306 (2012)
  10. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, A New Disilene with π-Accepting Groups from the Reaction of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) with Isocyanides J. Am. Chem. Soc. 134, 2954-2957 (2012)
  11. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, Access to a Stable Si2N2 4-Membered Ring with Non-Kekulé Singlet Biradical Character from a Disilyne J. Am. Chem. Soc. 133, 12478-12481 (2011)
  12. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, Hydroboration of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2), Giving Boryl-substituted Disilenes Organometallics 30, 2044-2050 (2011)
  13. Katsuhiko Takeuchi, Masao Ikoshi, Masaaki Ichinohe, Akira Sekiguchi, Silicon Version of Enamines: Amino-substituted Disilenes by the Reactions of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) with Amines J. Organomet. Chem. 696, 1156-1162 (2011)
  14. Katsuhiko Takeuchi, Masao Ikoshi, Masaaki Ichinohe, and Akira Sekiguchi, Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-substituted Disilenes J. Am. Chem. Soc. 132, 930-931 (2010)
  15. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, Jing-Dong Guo, Shigeru Nagase, A Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Bis(silylcyanide) Forming a 1,4-Diaza-2,3-disilabenzene Analogue J. Phys. Org. Chem. 23, 390-394 (2010)
  16. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, Jing-Dong Guo, Shigeru Nagase, Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Nitriles: Unexpected Formation of Triaza-1,4-disilabicyclo[2.2.2]oct-2,5,7-triene Derivatives Organometallics 28, 2658-2660 (2009)
  17. Katsuhiko Takeuchi, Masaaki Ichinohe, Akira Sekiguchi, Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Silylcyanide: Two Pathways to Form the Bis-Adduct [RSiSiR(CNSiMe3)2] with Some Silaketenimine Character and a 1,4-Diaza-2,3-disilabenzene Analogue J. Am. Chem. Soc. 130, 16848-16849 (2008)


Update: Jul 18,2017